: 26.3-4. Steam Distillation of Ethylaniline. A mixture contains 100 kg of H20 and 100 kg of ethylaniline (mol wt 121.1 kg/kg mol), which is
: 26.3-4. Steam Distillation of Ethylaniline. A mixture contains 100 kg of H20 and 100 kg
of ethylaniline (mol wt 121.1 kg/kg mol), which is immiscible with water. A very
slight amount of a nonvolatile impurity is dissolved in the organic. To purify the eth-
ylaniline, it is steam-distilled by bubbling saturated steam into the mixture at a total
pressure of 101.32 kPa (1 atm). Determine the boiling point of the mixture and the
composition of the vapor. The vapor pressure of each of the pure compounds is
follows (T1):
(XC
Тетрerature
PA (water)
(kPa)
PB (ethylaniline)
(kPa)
E400
В
°C
K
1.33
48.5
80.6
353.8
2.67
87.7
96.0
369.2
3.04
98.3
99.15
372.3
5.33
163.3
113.2
386.4
SCE
65
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